lib.Kubic module

class lib.EoS.Cubic.Kubic.Kubic(T, P, mezcla, **kwargs)[source]

Bases: Cubic

Kubic cubic equation of state, [1]

This is a two parameter cubic equation of state with both parameters temperature dependent

\[\begin{split}\begin{array}[t]{l} P = \frac{RT}{V-b}-\frac{a(T)}{\left(V+c\right)^2}\\ a(T) = \frac{27}{64} \frac{R^2T_c^2}{P_c} \left(\alpha^0\left(T_r\right)+\omega'\alpha^1\left(T_r\right)\right)\\ \alpha^0 = -0.1514T_r + 0.7895 + \frac{0.3314}{T_r} + \frac{0.029}{T_r^2} + \frac{0.0015}{T_r^7}\\ \alpha^1 = -0.237T_r - \frac{0.7846}{T_r} + \frac{1.0026}{T_r^2} + \frac{0.019}{T_r^7}\\ b = \left(0.082-0.0715\omega'\right)\frac{RT_c}{P_c}\\ c = \left(0.043\gamma^0\left(T_r\right)+0.0713\omega'\gamma^1 \left(T_r\right)\right)\frac{RT_c}{P_c}\\ \gamma^0 = 4.275051 - \frac{8.878889}{T_r} + \frac{8.508932}{T_r^2} - \frac{3.481408}{T_r^3} + \frac{0.576312}{T_r^4}\\ \gamma^1 = 12.856404 - \frac{34.744125}{T_r} + \frac{37.433095}{T_r^2} - \frac{18.059421}{T_r^3} + \frac{3.514050}{T_r^4}\\ \omega' = 0.000756+0.90984\omega+0.16226\omega^2+0.14549\omega^3\\ \end{array}\end{split}\]
_cubicDefinition(T)[source]

Definition of individual components coefficients

_GEOS(xi)[source]

Definition of parameters of generalized cubic equation of state, each child class must define in this procedure the values of mixture a, b, delta, epsilon. The returned values are not dimensionless.

Parameters:
xilist

Molar fraction of component in mixture, [-]

Returns:
parameterslist

Mixture parameters of equation, a, b, c, d

_lib(cmp, T)[source]

References